Molecular recognition in a uradinyl-functionalized stable radical

Literature Information

Publication Date 2004-12-17
DOI 10.1039/B411389F
Impact Factor 6.222
Authors

Patrick Taylor, Paul M. Lahti, Joseph B. Carroll, Vincent M. Rotello


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Abstract

Stable radical 2-(6-uradinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (1) binds to hydrogen-bonding complement 2,6-di(propylamido)pyridine (DAP) in chloroform with Ka = 220 M−1 at 33 °C; ESI-MS shows not only 1∶DAP complementary dyad formation, but also 1∶(DAP)2 formation at higher concentrations of DAP.

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DOI: 10.1039/JA99308BX007

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DOI: 10.1039/JA993080150R

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