Geometrical vs. statistical models for describing phase transition kinetics in thin films
Literature Information
Ellen H. G. Backus
We present calculations and simulations to investigate different theories describing phase transitions in thin films, with special emphasis on the growth of the new phase after nucleation. In particular, models with geometric and statistical growth rules are compared. It is demonstrated that the commonly employed geometrical approach, which assumes nucleation and subsequent radial growth of the newly formed phase, has distinct limitations for thin film systems. More realistic statistical Monte Carlo simulations that are governed by statistical growth rules, predict that a non-spherical (prolate) shape may develop after nucleation at or near a surface or interface. In addition, the predicted kinetics of the phase transformation is notably different for the geometric vs. the statistical model, for similar parameters. The simulation results are compared to recent experiments on the crystallization of thin amorphous solid water films.
Recommended Journals

Russian Chemical Bulletin

Russian Journal of Bioorganic Chemistry

Russian Journal of General Chemistry

Russian Journal of Applied Chemistry

Journal of Saudi Chemical Society

Organic Process Research & Development

Nature Medicine

Chemical Communications

Saudi Pharmaceutical Journal

Russian Journal of Coordination Chemistry
Related Literature
The reticent tautomer: exploiting the interesting multisite and multitype reactivity of 4-pyrrolin-2-ones
Tamsyn Montagnon, Dimitris Kalaitzakis, Manolis Sofiadis, Georgios Vassilikogiannakis
DOI: 10.1039/C9OB02471A
p-TsOH-mediated synthesis of substituted 2,4-diaryl-3-sulfonylquinolines from functionalized 2-aminobenzophenones and aromatic β-ketosulfones under microwave irradiation
Chieh-Kai Chan, Chien-Yu Lai, Wei-Chih Lo, Yu-Ting Cheng, Cheng-Chung Wang
DOI: 10.1039/C9OB02445J
Synthesis of trehalose glycolipids
Santanu Jana, Suvarn S. Kulkarni
DOI: 10.1039/D0OB00041H
Effect of n-alkyl substitution on Cu(ii)-selective chemosensing of rhodamine B derivatives
Santosh Kumar Mishra
DOI: 10.1039/C9OB02439E
Asymmetric total syntheses of naturally occurring α,β-enone-containing RALs, L-783290 and L-783277 through intramolecular base-mediated macrolactonization reaction
Joy Chakraborty, Samik Nanda
DOI: 10.1039/D0OB00237B
Total synthesis of isatindigotindoline C
Juha H. Siitonen, Sherlin Lira, Muhammed Yousufuddin, László Kürti
DOI: 10.1039/D0OB00270D
Examination of pinanediol–boronic acid ester formation in aqueous media: relevance to the relative stability of trigonal and tetrahedral boronate esters
Mayte A. Martínez-Aguirre, Marcos Flores-Alamo, Felipe Medrano, Anatoly K. Yatsimirsky
DOI: 10.1039/D0OB00201A
Stereoselective Michael additions on α-aminoacrylates as the key step to an l-Oic analogue bearing a quaternary stereocenter
Federico Maria Cecchinelli, Giuseppe Celentano, Alessandra Puglisi, Nicoletta Gaggero
DOI: 10.1039/C9OB02084E
δ-Cyano substituted para-quinone methides enable access to unsymmetric tri- and tetraarylmethanes containing all-carbon quaternary stereocenters
Yue Qi, Fang Zhang, Lin Wang, Aili Feng, Rongxiu Zhu, Shutao Sun, Wei Li, Lei Liu
DOI: 10.1039/D0OB00551G
You might also like
What regulatory guidelines apply to 6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1)?
6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1) falls under various...
Are there alternatives to 1-Pyrrolidineethanol, β-methyl-α-phenyl-, (αS,βR) (CAS: 123620-80-4) in synthesis?
While there are no direct alternatives, similar compounds like 1-Pyrrolidineetha...
Is 4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) safe?
4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) is ...
How should 2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) be stored?
2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) should be stored in a...
What are the physical and chemical properties of 4,5,6,7-Tetrahydro-1H-indazole hydrochloride (CAS: 18161-11-0)?
4,5,6,7-Tetrahydro-1H-indazole hydrochloride is a white crystalline solid with a...
What is (2R)-1-Methoxy-3-phenyl-2-propanamine (CAS: 59919-07-2)?
(2R)-1-Methoxy-3-phenyl-2-propanamine is a chiral organic compound with the CAS ...
What industries use Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate (CAS: 56649-47-9)?
Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate is used in various industries...
What regulatory guidelines apply to 4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3)?
4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3) falls...
What industries use (S)-3-Amino-5-phenylpentanoic acid hydrochloride (CAS: 331846-97-0)?
(S)-3-Amino-5-phenylpentanoic acid hydrochloride is primarily used in the pharma...
How is 7-methoxy-1-benzothiophene-2-carboxylic acid (CAS: 88791-07-5) typically synthesized?
7-Methoxy-1-benzothiophene-2-carboxylic acid is typically synthesized by reactin...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.


![Benzeneacetic acid, 2-[(2,6-dichlorophenyl)amino]-, compd. with 1-pyrrolidineethanol (1:1) structure Benzeneacetic acid, 2-[(2,6-dichlorophenyl)amino]-, compd. with 1-pyrrolidineethanol (1:1) structure](https://static.chemtradehub.com/structs/119/119623-66-4-5301.webp)
![2-Methyl-2-propanyl 4-{2-fluoro-5-[(4-oxo-3,4-dihydro-1-phthalazinyl)methyl]benzoyl}-1-piperazinecarboxylate structure 2-Methyl-2-propanyl 4-{2-fluoro-5-[(4-oxo-3,4-dihydro-1-phthalazinyl)methyl]benzoyl}-1-piperazinecarboxylate structure](https://static.chemtradehub.com/structs/763/763114-04-1-65a9.webp)
