A samarium cyclooctatetraene complex as catalyst for hydroamination/cyclisation catalysis

Literature Information

Publication Date 2004-09-30
DOI 10.1039/B410918J
Impact Factor 6.222
Authors

Agustino Zulys, Tarun K. Panda, Michael T. Gamer, Peter W. Roesky


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Abstract

The cyclooctatetraene-bis(phosphinimino)methanide complex [{CH(PPh2NSiMe3)2}Sm(η8-C8H8)] has been prepared; although this compound has no alkyl or amide ligand it shows moderate activity as a catalyst for the hydroamination/cyclisation reaction.

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Chemical Communications

Chemical Communications
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