Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(vi) complex as catalyst

Literature Information

Publication Date 2004-09-28
DOI 10.1039/B408946D
Impact Factor 6.222
Authors

Narottam Gharah, Santu Chakraborty, Alok K. Mukherjee, Ramgopal Bhattacharyya


View Original

Abstract

A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)] (saloxH2 = salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical.

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