Asymmetric Michael addition reactions of 2-silyloxyfurans catalyzed by binaphthyldiimine–Ni(ii) complexes

Literature Information

Publication Date 2004-05-17
DOI 10.1039/B402826K
Impact Factor 6.222
Authors

Hiroyuki Suga, Takeo Kitamura, Akikazu Kakehi, Toshihide Baba


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Abstract

N,N′-Bis(2-quinolylmethylene)-1,1′-binaphthyl-2,2′-diamine–Ni(II) complex and analogous complexes were found to be efficient chiral Lewis acid catalysts for the asymmetric Michael addition reactions between 2-silyloxyfurans and 3-alkenoyl-2-oxazolidinones, for which asymmetric inductions of up to 97% ee were obtained.

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