Two mixed-valence copper(i,ii) imidazolate coordination polymers: metal-valence tuning approach for new topological structures
Literature Information
Jie-Peng Zhang, Yan-Yong Lin, Xiao-Lan Yu, Xiao-Ming Chen
A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu2(im)3 and Cu3(im)4 (Him = imidazole), which are an unprecedented uninodal 4-connected 4.85 topological net and a 4-connected (4,4) net, respectively.
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