Two mixed-valence copper(i,ii) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

Literature Information

Publication Date 2004-04-01
DOI 10.1039/B401691B
Impact Factor 6.222
Authors

Jie-Peng Zhang, Yan-Yong Lin, Xiao-Lan Yu, Xiao-Ming Chen


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Abstract

A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu2(im)3 and Cu3(im)4 (Him = imidazole), which are an unprecedented uninodal 4-connected 4.85 topological net and a 4-connected (4,4) net, respectively.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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