Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation

Literature Information

Publication Date 2004-04-01
DOI 10.1039/B401537A
Impact Factor 6.222
Authors

C. André Ohlin, Paul J. Dyson, Gábor Laurenczy


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Abstract

The solubility of carbon monoxide in 37 ionic liquids and in some organic solvents has been determined using high-pressure 13C NMR spectroscopy; a method for predicting the CO solubility is demonstrated, and it was shown that the rate of the hydroformylation of 5-hexen-2-one does not correlate with the CO solubility, as expected from the determined relative solubility of CO compared to H2.

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