Ti–Mo heterobimetallic thiacalix[4]arene complex containing an unusual α-agostic μ2-η5:η2-cyclopentadienyl ligand

Literature Information

Publication Date 2004-02-26
DOI 10.1039/B316972C
Impact Factor 6.222
Authors

Shin Takemoto, Shinpei Tanaka, Yasushi Mizobe, Masanobu Hidai


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Abstract

A stepwise reaction of p-tert-butylthiacalix[4]arene (TC4A–(OH)4) with [CpTiCl3]–NEt3 and cis-[Mo(N2)2(PMe2Ph)4] afforded a new Ti–Mo heterobimetallic complex [TC4A–(O)4Ti(μ2-C5H5)MoH(PMe2Ph)2] which shows an unusual α-agostic μ2-η5:η2-coordination of a cyclopentadienyl ligand.

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