A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16)
Literature Information
Brian K. Nicholson, Brian W. Skelton, Allan H. White
Elimination of AuX(PR3) (X = halogen, R = Ph, tol) occurs readily in reactions between compounds containing C(sp)– or C(sp2)–X bonds and alkynyl or polyynyl gold(I) complexes; this reaction has been applied to the syntheses of complexes containing a variety of metal centres linked by Cn chains (n up to 16).
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