Solvent templated synthesis of metal–organic frameworks: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]·½DMF}n and {[Mn(dcbp)]·2H2O}n

Literature Information

Publication Date 2004-02-25
DOI 10.1039/B315483A
Impact Factor 6.222
Authors

Eithne Tynan, Paul Jensen, Paul E. Kruger, Anthea C. Lees


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Abstract

The identity of the metal–organic framework formed by Mn(II) and 4,4′-dicarboxy-2,2′-bipyridine (H2dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers {[Mn(dcbp)]·½DMF}n, 1, and {[Mn(dcbp)]·2H2O}n, 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.

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