Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components
Literature Information
Qiao-Hua Wei, Gang-Qiang Yin, Zhen Ma, Lin-Xi Shi
Reactions between the building blocks [Ag2(μ-Ph2PXPPh2)2(MeCN)2]2+ and [Pt(CCC6H4R-p)4]2− (R = H, CH3) afforded strongly luminescent acetylide-linked neutral heterohexanuclear complexes Pt2Ag4(μ-Ph2PNPPh2)4 (CCC6H4R-p)4 (R = H, 1; CH3, 2) for X = NH, but a heterotrinuclear complex cation [PtAg2(μ-PPh2CH2PPh2)2 (CCC6H5)2(CH3CN)2]2+ (32+) for X = CH2.
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