Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

Literature Information

Publication Date 2003-06-18
DOI 10.1039/B304814D
Impact Factor 6.222
Authors

Bárbara Gigante, Debasish Das, Mercedes Alvaro, Hermenegildo Garcia, Avelino Corma


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Abstract

A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.

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