Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)
Literature Information
Bárbara Gigante, Debasish Das, Mercedes Alvaro, Hermenegildo Garcia, Avelino Corma
A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.
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