Reversed effects of DNA on hydride transfer and electron transfer reactions of acridinium and quinolinium ions
Literature Information
Mari Nishimine, Kei Ohkubo, Takashi Komori, Shunichi Fukuzumi
DNA inhibits hydride transfer from 1-benzyl-1,4-dihydronicotinamide to the 10-methylacridinium ion, whereas DNA accelerates photoinduced electron transfer from the excited state of Ru(bpy)32+ to the 1-methylquinolinium ion. The reason of such reversed effects of DNA on the hydride transfer and electron transfer reactions is clarified.
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