Dome-distortion and fluorine-lined channels: synthesis, and molecular and crystal structure of a metal- and C–H bonds-free fluorophthalocyanine

Literature Information

Publication Date 2003-06-03
DOI 10.1039/B303035K
Impact Factor 6.222
Authors

Hyun-Jin Lee, William W. Brennessel, Joshua A. Lessing, William W. Brucker, Victor G. Young, Jr., Sergiu M. Gorun


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Abstract

The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for ∼ 39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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