Selective synthesis of conformationally restricted mono-cyclopentadienyl titanium(iv) complexes of p-tBu-calix[6]arene

Literature Information

Publication Date 2003-03-18
DOI 10.1039/B301075A
Impact Factor 6.222
Authors

Antonella J. Petrella, Nicholas K. Roberts, Donald C. Craig, Colin L. Raston, Robert N. Lamb


View Original

Abstract

Reaction of p-tBu-calix[6]arene with potassium metal in methanol followed by [TiCp2Cl2] affords novel mononuclear and binuclear monocyclopentadienyl titanium(IV) complexes, both having the same inverted double cone conformation with a Cp in one of the cavities, in both complexes.

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