8-(1,4,7,10-Tetraoxa-13-azacyclopentadec-13-ylmethyl)quinolin-7-ol: synthesis and application as a highly sensitive metal cation probe

Literature Information

Publication Date 2003-03-10
DOI 10.1039/B300941F
Impact Factor 6.222
Authors

Kun-Chan Wu, Moawia O. Ahmed, Chun-Yan Chen, Guo-Wei Huang, Yung-Son Hon, Pi-Tai Chou


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Abstract

A new metal ion probe 8-(1,4,7,10-tetraoxa-13-azacyclopentadec-13-ylmethyl)quinolin-7-ol (1a) was synthesized via a modified Mannich reaction, in which the mechanism of recognition incorporates excited-state proton transfer reactions. The remarkable differentiation in spectral properties upon metal complexation makes 1a a highly sensitive fluorescence probe.

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