A novel approach to carbon hollow spheres and vessels from CCl4 at low temperatures

Literature Information

Publication Date 2003-03-10
DOI 10.1039/B211996J
Impact Factor 6.222
Authors

Zhengquan Li, Changzheng Wu, Rong Zhang


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Abstract

Carbon hollow spheres (400–600 nm) and vessels (400 nm × 3000 nm) have been synthesized from sp3-CCl4 at 190 and 230 °C, respectively. The HRTEM images and Raman spectra reveal the sp2 nature of the as-obtained products, indicating that the transformation from carbon sp3 to sp2 occurs in the reactions. The possible mechanism has also been proposed.

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