Ion pair formation ia photoinduced proton transfer in excited hydroxynaphthalimide-N-methylimidazole hydrogen bonded complex: effect of temperature and viscosity on dual fluorescence

Literature Information

Publication Date 2001-03-19
DOI 10.1039/B100692O
Impact Factor 3.676
Authors

László Biczók, Pierre Valat, Véronique Wintgens


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Abstract

The kinetics of photoinduced processes in the hydrogen bonded complex between N-methyl-3-hydroxynaphthalimide and 1-methylimidazole was studied in a wide temperature range in ethyl acetate and glycerol triacetate. The proton transfer within the excited complex was found to be very fast because of its negligible activation energy. The fairly intense dual fluorescence was assigned to hydrogen bonded and solvent separated ion pairs. Kinetic parameters for the various deactivation pathways of these excited species were derived from the combined analysis of the steady-state and the time-resolved fluorescence results. The Arrhenius pre-exponential factor of the transition from the solvent separated into the hydrogen bonded ion pair proved to be more than two orders of magnitude larger in glycerol triacetate compared with that in ethyl acetate, whereas the other processes showed less viscosity dependence. The radiationless energy dissipation rate of the hydrogen bonded ion pair was insensitive to the experimental conditions. However, thermal enhanced internal conversion was observed for the solvent separated ion pair.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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