Aromatization of cyclic hydrocarbons via thioether elimination reaction

Literature Information

Publication Date 2023-08-25
DOI 10.1039/D3CC03279E
Impact Factor 6.222
Authors

Yang Liu, Yingqi Feng, Jinli Nie, Sijie Xie, Xin Pen, Huanliang Hong, Xiuwen Chen, Lu Chen, Yibiao Li


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Abstract

Herein, the diversity-oriented aromatization of cyclic hydrocarbons via potassium ethyl xanthogenate (EtOCS2K)/NH4I-mediated methylthiyl radical addition and thioether elimination was investigated under transition-metal-free conditions. The methylthiyl radical species were generated in situ via the NH4I-mediated decomposition of DMSO following which EtOCS2K promoted the breaking of carbon–sulfur bonds of thioether.

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