Tuning the photophysical properties of luminescent lanthanide complexes through regioselective antenna fluorination

Literature Information

Publication Date 2022-05-18
DOI 10.1039/D2CC01229D
Impact Factor 6.222
Authors

Daniel Kocsi, Andreas Orthaber, K. Eszter Borbas


View Original

Abstract

Carbostyrils monofluorinated in the 3, 5, or 6 positions were synthesised from olefinic precursors via a photochemical isomerisation-cyclisation route, and incorporated into octadentate cyclen triacetate ligands that formed luminescent complexes with Tb(III) and Eu(III). The photophysical properties of the emitters were strongly dependent on the position of the fluorination.

Related Literature

Redox-sensitive hyaluronic acid–paclitaxel conjugate micelles with high physical drug loading for efficient tumor therapy

Tingjie Yin, Jing Wang, Lifang Yin, Linjia Shen, Jianping Zhou, Meirong Huo

2015-09-24 Paper

DOI: 10.1039/C5PY01355K

Synthesis and hydrolytic properties of water-soluble poly(carbonate–hydroxyurethane)s from trimethylolpropane

Hiroyuki Matsukizono, Takeshi Endo

2015-12-08 Paper

DOI: 10.1039/C5PY01733E

Supramolecular fluorescent nanoparticles functionalized with controllable physical properties and temperature-responsive release behavior

Chih-Chia Cheng, Jyun-Jie Huang, Adem Ali Muhable, Zhi-Sheng Liao, Shan-You Huang, Shun-Chieh Lee, Chih-Wei Chiu

2017-03-09 Paper

DOI: 10.1039/C7PY00276A

Robust carboxylated polymer pores from a cyclic peptide template

Mahesh Potnuru, Nandita Madhavan

2015-10-21 Communication

DOI: 10.1039/C5PY01313E

Controlled radical polymerization and in-depth mass-spectrometric characterization of poly(ionic liquid)s and their photopatterning on surfaces

Birgit Huber, Vanessa Trouillet, Steffen M. Weidner, Leonie Barner, Peter W. Roesky, Jiayin Yuan

2015-10-26 Paper

DOI: 10.1039/C5PY01320H

Front cover

Cover

DOI: 10.1039/C5PY90185E

Front cover

Cover

DOI: 10.1039/C6PY90007K

Synthesis of photoresponsive polymeric propesticide micelles based on PEG for the controlled release of a herbicide

Kaikai Ding, Liyan Shi, Ling Zhang, Tian Zeng, Yihua Yin, Ying Yi

2015-12-03 Paper

DOI: 10.1039/C5PY01690H

One-pot synthesis of poly(vinylidene fluoride) methacrylate macromonomers via thia-Michael addition

Marc Guerre, Bruno Ameduri, Vincent Ladmiral

2015-11-03 Paper

DOI: 10.1039/C5PY01651G

Front cover

Cover

DOI: 10.1039/C7PY90058A

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.