C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands

Literature Information

Publication Date 2022-02-28
DOI 10.1039/D2CC00639A
Impact Factor 6.222
Authors

Sanjay Adhikari, Aniruddha Sarkar, Basab Bijayi Dhar


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Abstract

Ni(II)-tetradentate amido-quinoline complexes effectively catalysed C–H chlorination of a series of hydrocarbons in the presence of NaOCl and acetic acid. The bond dissociation energy of the C(sp3)–H bond of the substrates varies from 99.3 kcal mol−1 (cyclohexane) to 87 kcal mol−1 (ethyl benzene). Exclusively chlorinated products (TON: 220 for cyclohexane) were obtained without any hydroxylated products, thus mimicking the activity of the halogenase enzyme.

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