Micro-kinetic model of electrochemical carbon dioxide reduction over platinum in non-aqueous solvents
Literature Information
Brian A. Rohr, Aayush R. Singh, Joseph A. Gauthier, Michael J. Statt, Jens K. Nørskov
The competition between the hydrogen evolution reaction and the electrochemical reduction of carbon dioxide to multi-carbon products is a well-known challenge. In this study, we present a simple micro-kinetic model of these competing reactions over a platinum catalyst under a strong reducing potential at varying proton concentrations in a non-aqueous solvent. The model provides some insight into the mechanism of reaction and suggests that low proton concentration and a high fraction of stepped sites is likely to improve selectivity to multi-carbon products.
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