Cu/SAPO-34 prepared by a facile ball milling method for enhanced catalytic performance in the selective catalytic reduction of NOx with NH3
Literature Information
Huazhen Chang, Xuan Qin, Lei Ma, Tao Zhang, Junhua Li
Cu/SAPO-34 catalysts were prepared by different solid-state ion exchange methods, i.e., mechanical mixing (Cu/SAPO-34-M) and ball milling (Cu/SAPO-34-B), and were used for selective catalytic reduction of NOx with NH3 (NH3-SCR) reaction. Compared with Cu/SAPO-34-M, Cu/SAPO-34-B exhibited more excellent NH3-SCR catalytic activity. Various characterization methods, including XRD, SEM, N2 adsorption–desorption, UV-vis, H2-TPR, EPR, NO + O2-TPD, NH3-TPD, and in situ DRIFTS, were used to elucidate their different catalytic performances. The characterization results suggested that ball milling could be beneficial for increasing the amount of isolated Cu2+ ions in the Cu/SAPO-34 catalyst. In comparison with Cu/SAPO-34-M, Cu/SAPO-34-B had more isolated Cu2+ ions, which mainly contributed to the NOx adsorption and Lewis acid sites. Furthermore, ball milling could improve the redox property of the Cu/SAPO-34 catalyst. The in situ DRIFTS results verified that NH3 adsorbed on Lewis acid sites were more active than those adsorbed on Brønsted acid sites. Therefore, it was believed that ball milling was a suitable method to prepare more efficient Cu/SAPO-34 catalysts for NOx removal from diesel exhaust.
Related Literature
An enantioselective fluorescence sensing assay for quantitative analysis of chiral carboxylic acids and amino acid derivatives
Christian Wolf, Shuanglong Liu, Brian C. Reinhardt
DOI: 10.1039/B609880K
Hydrophosphinylation of unactivated alkenes with secondary phosphineoxides under visible-light photocatalysis
Woo-Jin Yoo, Shū Kobayashi
DOI: 10.1039/C3GC40482J
Tuning the photophysical properties of luminescent lanthanide complexes through regioselective antenna fluorination
Daniel Kocsi, Andreas Orthaber, K. Eszter Borbas
DOI: 10.1039/D2CC01229D
Enhanced accumulation of microalgal pigments using metal nanoparticle solutions as light filtering devices
Paul K. Eggers, Matthew Winslade, Steven M. Smith, Colin L. Raston
DOI: 10.1039/C3GC41291A
Polypropylene fiber supported ionic liquids for the conversion of fructose to 5-hydroxymethylfurfural under mild conditions
Xian-Lei Shi, Min Zhang, Yongdan Li, Wenqin Zhang
DOI: 10.1039/C3GC41565A
Aza-Michael versus aminolysis reactions of glycerol carbonate acrylate
Nohra Bassam, Candy Laure, Blanco Jean-François, Raoul Yann, Mouloungui Zephirin
DOI: 10.1039/C3GC37054B
Palladium-catalyzed difluoroalkylative carbonylation of styrenes toward difluoropentanedioates
Youcan Zhang
DOI: 10.1039/D2SC02665A
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure (2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure](https://static.chemtradehub.com/structs/250/2505001-54-5-c1e9.webp)



