Role of direct and inverted undoped spiro-OMeTAD–perovskite architectures in determining solar cells performances: an investigation via electrical impedance spectroscopy

Literature Information

Publication Date 2019-02-22
DOI 10.1039/C9CP00564A
Impact Factor 3.676
Authors

Marianna Ambrico, Paolo F. Ambrico, Luisa De Marco, Rosabianca Iacobellis, Arianna D’Abramo, Teresa Ligonzo


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Abstract

The present study involved an investigation on the reasoning behind the dependence of the perovskite solar cells photovoltaic efficiencies on the relative position of the undoped spiro-OMeTAD hole-transport material with respect to the perovskite in the device. We adopted impedance spectroscopy to investigate the modification of the carrier transport mechanisms across the spiro-OMeTAD/perovskite interface constituting the active part where the main device processes occur. We investigated two interface structures, referred to as the direct (or regular, n–i–p) and the inverted (p–i–n) configuration. This work also intended to further stress the possible adoption of alternative device structures working with undoped hole-transport materials.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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