Preparation of semifluorinated poly(meth)acrylates by improved photo-controlled radical polymerization without the use of a fluorinated RAFT agent: facilitating surface fabrication with fluorinated materials

Literature Information

Publication Date 2018-07-11
DOI 10.1039/C8PY00990B
Impact Factor 5.582
Authors

Qinzhi Quan, Honghong Gong, Mao Chen


View Original

Abstract

Fluorinated polymers have attracted increasing attention in a broad range of areas, and access to such polymers with low-cost agents and simple conditions would offer improved application opportunities for both academia and industry. An efficient preparation of a variety of semifluorinated poly(meth)acrylates without the use of a fluorinated iniferter/initiator or a solvent via photo-controlled radical polymerization is herein reported. The polymerizations can be efficiently switched between “ON” and “OFF” both in the presence and absence of a photoredox catalyst in response to visible light while maintaining a linear increase in polymer molar mass with conversion and first order kinetics. As demonstrated with gel permeation chromatography analysis and kinetic investigations, catalyzed photopolymerizations provide polymers with narrower molar mass distributions, shorter induction times and higher conversions in comparison with catalyst-free reactions, representing a reliable and efficient synthetic approach starting off from fluorine-free agents. The high chain-end fidelity of the polymer was confirmed by MALDI-TOF-MS measurements and chain-extension experiments. Furthermore, the method using fluorine-free iniferters facilitated surface fabrication with fluoropolymers, providing highly hydrophobic materials. These results illustrate the simplicity and utility of the light-controlled polymerization of semifluorinated monomers.

Related Literature

PVA-based bulk microneedles capable of high insulin loading and pH-triggered degradation for multi-responsive and sustained hypoglycemic therapy

Yuhong Ma, Wei Wang, Mujiao He, Yunzhu Liu, Caihua Li, Yinan Zhong, Quanmin Bu, Dechun Huang, Hongliang Qian, Wei Chen

2023-12-01 Paper

DOI: 10.1039/D3BM01760E

A dual-mode green emissive fluorescent probe for real-time detection of doxycycline in milk using a smartphone sensing platform

Ruiqing Sun, Ping Liu, Yingjia Dong, Qingli Yang, Yongchao Ma

2023-11-14 Paper

DOI: 10.1039/D3AY01850D

Enhancing drug delivery with supramolecular amphiphilic macrocycle nanoparticles: selective targeting of CDK4/6 inhibitor palbociclib to melanoma

Mohamed F. Attia, Edikan A. Ogunnaike, Megan Pitz, Nancy M. Elbaz, Dillip K. Panda, Angela Alexander-Bryant, Sourav Saha, Daniel C. Whitehead

2023-12-11 Paper

DOI: 10.1039/D3BM01888A

A robust method to improve the regression accuracy of LIBS data: determination of heavy metal Cu in Tegillarca granosa

Jie Huang, Xiaojing Chen, Zhonghao Xie, Shujat Ali, Xi Chen, Leiming Yuan, Chengxi Jiang, Guangzao Huang, Wen Shi

2023-11-14 Paper

DOI: 10.1039/D3AY01411H

Biosynthesized tumor acidity and MMP dual-responsive plant toxin gelonin for robust cancer therapy

Huiyan Cao, Chenchen Zhu, Fangyuan Chen, Jiaqi Ye, Bin-Chun Li, Peng Yang, Mingqiang Qiao, Zhuoyu Li

2023-12-05 Paper

DOI: 10.1039/D3BM01779F

Detection of coca alkaloids in oral fluid from coca leaf (tea) consumers: using solid phase extraction to improve validation parameters and widen the detection window

I. Álvarez-Freire, P. Cabarcos-Fernández, N. C. Rubio, A. Moreda-Piñeiro, M. J. Tabernero-Duque, I. Sánchez-Sellero, P. Bermejo-Barrera, A. M. Bermejo-Barrera

2023-10-18 Paper

DOI: 10.1039/D3AY01298K

A homogeneous label-free electrochemical aptasensor based on an omega-like DNA nanostructure for progesterone detection

Zaofen Wang, Weiping Shi, Yunzhu Tan, Bingqian Liu

2023-11-13 Paper

DOI: 10.1039/D3AY01255G

On site separation of inorganic forms of thallium and arsenic in sea water systems followed by ICP-MS determination

Joanna Kowalska, Alicja Drwal, Klaudia Tutaj, Lidiia Kovshun, Beata Krasnodębska-Ostręga

2023-11-06 Paper

DOI: 10.1039/D3AY01292A

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
Articles per Year: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.