6-CHLORO-2,3-DIOXO-1,2,3,4-TETRAHYDROQUINOXALINE, 97
CAS Number:
169-14-2
Molecular Formula:
C8H5ClN2O2
Regioselective living polymerization of allylcyclohexane and precise synthesis of hydrocarbon block copolymers with cyclic units
Literature Information
Publication Date
2018-02-07
DOI
10.1039/C8PY00047F
Impact Factor
5.582
Authors
Jie Gao, Zonghang Ying, Liu Zhong, Heng Liao, Haiyang Gao, Wu Qing
View Original
Abstract
Precise control over macromolecular structures is a central goal and remains a great challenge in synthetic polymer chemistry. We report herein the living isomerization polymerization of allycyclohexane (ACH) using α-diimine nickel catalysts with high regioselectivity. The influences of catalyst structure, cocatalyst, and temperature on ACH polymerization were studied in detail. The macromolecular structure of polyallycyclohexanes (PACHs) was precisely controlled by living polymerization in combination with high regioselectivity under optimized conditions. A mechanistic model involving the 2,1-insertion selectivity of ACH and chain walking was proposed. Well-defined polyallycyclohexane-b-poly(1-hexene) copolymers (PACH-b-PH) with cyclic units were synthesized by sequential monomer addition.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-Methyl-3-morpholinecarboxylic acid hydrochloride (1:1)
CAS Number:
1240518-90-4
Molecular Formula:
C6H12ClNO3
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(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid
CAS Number:
1269757-29-0
Molecular Formula:
C15H19NO4
![N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure](https://static.chemtradehub.com/structs/109/109032-22-6-7c88.webp "N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure")
N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide
CAS Number:
109032-22-6
Molecular Formula:
C13H12N2O6S
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