Antiferromagnetic ordering based on intermolecular London dispersion interactions in amphiphilic TEMPO ammonium salts
Literature Information
Jessica Exner, Steffen Eusterwiemann, Oliver Janka, Oliver Niehaus, Constantin G. Daniliuc, Rainer Pöttgen, Armido Studer
Antiferromagnetic coupling in TEMPO-based radicals can be enhanced via self-assembly through London dispersion interactions in amphiphilic solids. The synthesis, magnetic characterization, and three crystal structures of the solid radical ion salts (R-DMAT-n)X with various counterions X and alkyl chain lengths n are reported. Magnetic susceptibility and absolute EPR signal intensity measurements show singlet–triplet transitions in a number of cases, which is discussed in relation to the crystal structures. Antiferromagnetic ordering effects are sensitive to both the length of the alkyl chain and the counter anion.
Recommended Journals
Related Literature
Nitroxide mediated polymerization of methacrylates at moderate temperature
Christophe Detrembleur, Christine Jérôme, Julien De Winter, Pascal Gerbaux, Jean-Louis Clément, Yohann Guillaneuf, Didier Gigmes
DOI: 10.1039/C3PY01133J
Enzyme-mediated fast injectable hydrogels based on chitosan–glycolic acid/tyrosine: preparation, characterization, and chondrocyte culture
Rong Jin, Chao Lin, Aoneng Cao
DOI: 10.1039/C3PY00864A
A biomimic pH-sensitive polymeric prodrug based on polycarbonate for intracellular drug delivery
Haibo Wang, Yin Wang, Yangjun Chen, Qiao Jin, Jian Ji
DOI: 10.1039/C3PY00861D
pH-sensitive pullulan-based nanoparticles for intracellular drug delivery
Yinsong Wang, Yang Liu, Yuanyuan Liu, Yan Wang, Jing Wu, Rongshan Li, Jinrong Yang
DOI: 10.1039/C3PY00817G
Polyacetylenes containing BODIPY pendants with different connectivities: synthesis, characterization and opto-electronic properties
Bin Liu, Lingfeng Li, Cuiling Lin, Jingdan Zhou, Zhexin Zhu, Hongyao Xu, Huayu Qiu, Shouchun Yin
DOI: 10.1039/C3PY01021J
Manganese(iii) acetylacetonate initiated RAFT polymerizations: an alternative and versatile RAFT initiator
Zhigui Zheng, Yuan Zhou, Zhengbiao Zhang, Xiulin Zhu
DOI: 10.1039/C3PY00879G
Sunlight induced atom transfer radical polymerization by using dimanganese decacarbonyl
Mustafa Ciftci
DOI: 10.1039/C3PY01009K
Precise synthesis of a rod-coil type miktoarm star copolymer containing poly(n-hexyl isocyanate) and aliphatic polyester
Toshifumi Satoh, Naoki Nishikawa, Daisuke Kawato, Daichi Suemasa, Sungmin Jung, Young Yong Kim, Moonhor Ree, Toyoji Kakuchi
DOI: 10.1039/C3PY00985H
Micellar-cluster association of ureidopyrimidone functionalized monochelic polybutadiene
Sachin Laxman Bobade, Thomas Malmgren
DOI: 10.1039/C3PY01002C
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure (3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure](https://static.chemtradehub.com/structs/126/1269757-29-0-c552.webp)



