Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage
Literature Information
Publication Date
2017-12-04
DOI
10.1039/C7QO00927E
Impact Factor
5.281
Authors
Qi Yang, Liang Liu, Yue Chi, Wei Hao, Wen-Xiong Zhang
View Original
Abstract
A Rh(I)-catalyzed intramolecular cis-carbosilylation of alkynes was achieved. The cleavage of an alkyl–Si bond in a trimethylsilyl group of 8-alkynyl naphthalene derivatives was followed by cis-addition to the alkynyl moiety, affording silatricyclic compounds in good yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
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