Multiple noncovalent interaction constructed polymeric supramolecular crystals: recognition of butyl viologen by para-dicyclohexanocucurbit[6]uril and α,α′,δ,δ′-tetramethylcucurbit[6]uril
Literature Information
Publication Date
2017-09-05
DOI
10.1039/C7QO00708F
Impact Factor
5.281
Authors
Zhi-You Xiao, Rui-Lian Lin, Zhu Tao, Qing-Yun Liu, Jing-Xin Liu, Xin Xiao
View Original
Abstract
Binding interactions of butyl viologen (BV+) with para-dicyclohexanocucurbit[6]uril (Cy2Q[6]) and α,α′,δ,δ′-tetramethyl cucurbit[6]uril (TMeQ[6]) were investigated by 1H NMR spectroscopy, isothermal titration calorimetry (ITC) and X-ray crystallography. In the solid state, the BV+ guest and both hosts form polymeric supramolecular crystals through multiple noncovalent interactions, including host–guest interaction, π–π stacking interaction, and metal–host coordination. In the aqueous solution, the butyl chain of BV+ was selectively encapsulated into the hosts Cy2Q[6] and TMeQ[6], while the bipyridinium group resides outside of the host portals, forming [2]pseudorotaxane. The ITC experiment indicates that the host–guest binding processes are exclusively enthalpy driven.
Related Literature
Photostability and solvation: photodynamics of microsolvated zwitterionic glycine
2010-02-11
Paper
DOI: 10.1039/B925246K
Matrix isolation studies on the co-condensation reactions of molecular SiO and GeO: the characterisation of the novel cyclic species SiGeO2, Si2GeO3 and SiGe2O3
J. Steven Ogden, David C. Harrowven, Robert S. Wyatt, Francesco Ferrante, John P. Cannady
2010-04-22
Paper
DOI: 10.1039/C001453B
Formation of electro-conductive titanium oxide fine particles by pulsed UV laser irradiation
Tsutomu Ioroi, Hiroyuki Kageyama, Tomoki Akita, Kazuaki Yasuda
2010-06-08
Paper
DOI: 10.1039/B923218D
NO2 quantum yields from ultraviolet photodissociation of methyl and isopropyl nitrate
Paula Gorrotxategi Carbajo, Andrew J. Orr-Ewing
2010-04-20
Paper
DOI: 10.1039/C001425G
Polychlorinated trityl radicals for dynamic nuclear polarization: the role of chlorine nuclei
Juan Carlos Paniagua, Cristina Gabellieri, Miguel Feliz, Nans Roques
2010-05-10
Paper
DOI: 10.1039/C003291N
The chemical roots of the matching polynomial
Patrick W. Fowler, Jean-Paul Malrieu
2010-04-06
Paper
DOI: 10.1039/B923893J
Ab initio static and molecular dynamics study of the absorption spectra of the 4-styrylpyridine photoswitch in its cis and trans forms
Latévi Max Lawson Daku, Jorge Linares, Marie-Laure Boillot
2010-04-13
Paper
DOI: 10.1039/B920850J
Iron phthalocyanine in non-aqueous medium forming layer-by-layer films: growth mechanism, molecular architecture and applications
Maria Luz Rodríguez-Méndez, Jose Antonio De Saja Saez, Carlos José Leopoldo Constantino
2010-03-02
Paper
DOI: 10.1039/B922242C
Synthesis and microstructure of manganese ferrite colloidal nanocrystals
D. Carta, M. F. Casula, P. Floris, A. Falqui, G. Mountjoy, A. Boni, C. Sangregorio, A. Corrias
2010-04-08
Paper
DOI: 10.1039/B922646J
You might also like
Compound Q&A
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
40716-16-34-Methyl-6-(trifluor...
Compound Q&A
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
405058-00-64-(3,5-Difluoropheny...
Compound Q&A
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
338982-07-35-{[4-(Trifluorometh...
Compound Q&A
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
6317-57-34-Benzylaniline hydr...
Compound Q&A
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
115929-62-93-Bromo-2,5-dimethox...
Compound Q&A
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
24828-96-4Carbamic acid, N-[(5...
Compound Q&A
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
1298101-47-92-Methyl-2-propanyl ...
Compound Q&A
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
367-33-9Ethyl 2-bromo-4,4,4-...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
1,3(2H,4H)-Isoquinolinedione, 7-amino-4,4-dimethyl-
CAS Number:
14576-22-8
Molecular Formula:
C11H12N2O2
![(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure](https://static.chemtradehub.com/structs/126/1269757-29-0-c552.webp "(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure")
(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid
CAS Number:
1269757-29-0
Molecular Formula:
C15H19NO4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.