Enantio- and diastereoselective synthesis of tetrahydrofuro[2,3-b]furan-2(3H)-one derivatives and related oxygen heterocycles via an asymmetric organocatalytic cascade process
Literature Information
Publication Date
2017-08-28
DOI
10.1039/C7QO00621G
Impact Factor
5.281
Authors
Wei-Wei Zhao
View Original
Abstract
Tetrahydrofuro[2,3-b]furan-2(3H)-one derivatives bearing four stereogenic centers were achieved via an asymmetric organocatalytic cascade process with excellent stereoselectivity in one single operation and H2O as the only side product. The α,β-unsaturated carboxylic acid plays two important roles in the cascade process: the Michael acceptor and acidic co-catalyst for enamine catalysis.
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Organic Chemistry Frontiers
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