1,2,3-Triazole-assisted C–H amidation by cobalt(iii) catalysis
Literature Information
Publication Date
2017-08-10
DOI
10.1039/C7QO00556C
Impact Factor
5.281
Authors
Xinling Yu, Qiang Ma, Songyang Lv, Jue Li, Chen Zhang, Li Hai, Qiantao Wang, Yong Wu
View Original
Abstract
A procedure for the [Cp*CoIII]-catalyzed, 1,2,3-triazole directed C–H amidation of arenes, using dioxazolone as an efficient amidating reagent, has been developed. This reaction provides a step- and atom-economical protocol for C–N bond formation, releasing carbon dioxide as a single byproduct. Yet a variety of functional groups are well tolerated, obtaining the desired products in moderate to excellent yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid
CAS Number:
1269757-29-0
Molecular Formula:
C15H19NO4
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Molecular Formula:
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