Ir(iii)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation
Literature Information
Publication Date
2017-08-11
DOI
10.1039/C7QO00542C
Impact Factor
5.281
Authors
Wenge Zhang, Hong Deng, Hongji Li
View Original
Abstract
An efficient ortho C–H amidation of azoxybenzenes with 1,4,2-dioxazol-5-ones under Ir(III)-catalysis has been developed. This simple amidation reaction provides a new protocol for the diversification of azoxybenzenes, and affords the aminated products in moderate to good yields. Meanwhile, an investigation of the late-stage transformation of products is also presented in this text.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure](https://static.chemtradehub.com/structs/143/1434747-57-5-fc0d.webp "1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure")
1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile
CAS Number:
1434747-57-5
Molecular Formula:
C21H22BN3O4S
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