Palladium-catalyzed C(sp2)–H aminoimidoylation of isocyano-containing arenes: synthesis of amino substituted N-heterocycles
Literature Information
Publication Date
2017-06-06
DOI
10.1039/C7QO00368D
Impact Factor
5.281
Authors
Zhuang Xiong, Jian Wang, Yanbo Wang, Shuang Luo, Qiang Zhu
View Original
Abstract
An efficient access to amino substituted phenanthridine and isoquinoline derivatives, through palladium-catalyzed C(sp2)–H aminoimidoylation, has been developed. This process applies O-benzoyl hydroxylamines as oxidative amino sources to generate amino Pd(II) intermediates, followed by isocyanide insertion and intramolecular C(sp2)–H activation. Sequential C–N and C–C bond formation took place on isocyano-containing arenes in one step.
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Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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