Photoredox catalytic intramolecular imine C–H bond functionalization using ligand free Cu(ii) salts
Literature Information
Publication Date
2017-07-06
DOI
10.1039/C7QO00348J
Impact Factor
5.281
Authors
Xuhong Ren, Qiyang Wang, Wenjia Yu, Xiaoyu Zhan, Yishan Yao, Bingjie Qin, Mingxin Dong, Xinhua He
View Original
Abstract
Photocatalysis is a powerful method for organic synthesis because of the lack of side products/waste materials and high efficiency, but suitable reaction types are still underexplored. Inspired by the function of a directing group for C–H bond activation, we induce the directing group notion into photocatalysis to activate the C–H bond through light treatment only if any metal-directing group complexes are photoinitiators. Herein, we found that conjugated N,O-bidentate copper(II) complexes were novel photoinitiators, and thereby could be used as the directing group to activate their intramolecular imine C(sp2)–H to produce the corresponding cyclized products via a UV triggered free radical mechanism.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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Molecular Formula:
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