Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

Literature Information

Publication Date 2017-05-10
DOI 10.1039/C7QO00228A
Impact Factor 5.281
Authors

Yuhan Zhou, Huan Wang, Yang Liu, Yilong Zhao, Chunxia Zhang, Jingping Qu


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Abstract

An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato)diboron (B2pin2) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.

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