Palladium-catalyzed C–S bond activation and functionalization of 3-sulfenylindoles and related electron-rich heteroarenes
Literature Information
Publication Date
2017-05-10
DOI
10.1039/C7QO00215G
Impact Factor
5.281
Authors
Jianxiao Li, Yanni An, Jiawei Li, Shaorong Yang, Wanqing Wu, Huanfeng Jiang
View Original
Abstract
A novel and efficient palladium-catalyzed approach for copper-mediated C–S bond activation and functionalization of 3-sulfenylheteroarenes has been established. This protocol features good functional group compatibility and a broad substrate scope, and can serve as a powerful synthetic tool for the construction and late-stage modification of important heteroarene scaffolds. Remarkably, both the N-protected and free N–H indoles were nicely suitable for this transformation.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure](https://static.chemtradehub.com/structs/109/109032-22-6-7c88.webp "N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure")
N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide
CAS Number:
109032-22-6
Molecular Formula:
C13H12N2O6S
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