Precise syntheses of structurally possible all tetrablock quaterpolymers by a methodology combining living anionic polymerization with linking chemistry using 1 : 1 addition reaction
Literature Information
Publication Date
2017-12-14
DOI
10.1039/C7PY01948C
Impact Factor
5.582
Authors
Yuri Matsuo
View Original
Abstract
A methodology combining living anionic polymerization with linking chemistry using 1 : 1 addition reaction has been developed for the syntheses of tetrablock quaterpolymers composed of A, B, C, and D blocks. With this methodology using the ω-chain-end-(α-phenylacrylate (PA))-functionalized D, α,ω-chain-end-(2-tetrahydropyranyl ether and PA)-functionalized D, and ω-chain-end-PA-functionalized AD as the building blocks, the following all structurally possible twelve tetrablock quaterpolymers were successfully synthesized: ABCD, ABDC, ACBD, ACDB, ADBC, ADCB, BACD, BADC, BCAD, BDAC, CABD, and CBAD. Polystyrene, poly(2-vinylpyridine), poly(tert-butyl methacrylate) (or poly(methyl methacrylate)), and poly(1,2-butylene oxide) prepared by living anionic polymerization were used as A, B, C, and D blocks, respectively. The polymers synthesized in this study are quite new tetrablock quaterpolymers and well-defined in structure.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)
CAS Number:
1260803-10-8
Molecular Formula:
C8H9BrClNO
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