Main-chain benzoxazine precursor block copolymers

Literature Information

Publication Date 2017-11-28
DOI 10.1039/C7PY01873H
Impact Factor 5.582
Authors

Zeynep Deliballi, Baris Kiskan, Yusuf Yagci


View Original

Abstract

A novel strategy for the preparation of block copolymers of polymeric benzoxazine precursors with polyetheramines by one-pot two-step or stepwise pathways is described. The method pertains to the use of simple chemicals such as 4-hydroxyaniline, formaldehyde and polyetheramines (Jeffamines). The structures and molecular weights of the polymers were characterized by FTIR, 1H NMR, and GPC. Successful block copolymer formation was evidenced by the clear shift of the molecular weight of the block copolymer to the higher molecular weight region. Thermal properties of the polymers were also investigated by using DSC and TGA. Block copolymers were shown to undergo thermally activated curing by the ring-opening polymerization of the benzoxazine block. The thermal stability of the cured product drastically increased compared to the precursor polyetheramine.

Related Literature

Nitrile hydrogenation to secondary amines under ambient conditions over palladium–platinum random alloy nanoparticles

Yoshihide Nishida, Chandan Chaudhari, Hiroshi Yamada, Takaaki Toriyama, Tomokazu Yamamoto, Susan Meñez Aspera, Hiroshi Nakanishi, Katsutoshi Nagaoka

2022-03-01 Paper

DOI: 10.1039/D1CY02302K

Conversion of glucose and cellulose into value-added products in water and ionic liquids

Jinliang Song, Honglei Fan, Jun Ma, Buxing Han

2013-07-31 Tutorial Review

DOI: 10.1039/C3GC41141A

C–H bond chlorination using nickel(ii) complexes of tetradentate amido-quinoline ligands

Sanjay Adhikari, Aniruddha Sarkar, Basab Bijayi Dhar

2022-02-28 Communication

DOI: 10.1039/D2CC00639A

Variation from closed-shell to open shell electronic structures in oligothiophene bis(dioxolene) complexes

Paul D. Miller, David A. Shultz, Joshua Mengell, Lukasz Wojtas

2023-10-09 Edge Article

DOI: 10.1039/D3SC02341A

Correction: Activity-based NIR fluorescent probes based on the versatile hemicyanine scaffold: design strategy, biomedical applications, and outlook

Heejeong Kim, Jingjing Han, Qichao Yao, Juyoung Yoon

2022-02-21 Correction

DOI: 10.1039/D2CS90019J

MOF/COF hybrids as next generation materials for energy and biomedical applications

Cigdem Altintas, Ilknur Erucar, Seda Keskin

2022-10-14 Highlight

DOI: 10.1039/D2CE01296K

Back cover

Cover

DOI: 10.1039/C3GC90043F

Encapsulation of N-containing compounds in a new hydrophilic Cd-based crystalline sponge via coordinative alignment method

Faiza Habib, Derek A. Tocher, Claire J. Carmalt

2023-08-11 Paper

DOI: 10.1039/D3CE00592E

A rotatable cathode with tunable steric hindrance for high-performance aluminum organic batteries

Mingshan Han, Qinqin Zhou, Meng Zhang, Jinshu Wang, Fangyan Cui, Yunfei Yang, Jingwen Su, Weiwei Huang, Yuxiang Hu

2023-05-16 Paper

DOI: 10.1039/D3TA00343D

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
Articles per Year: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.