Aziridine-functionalized polydimethylsiloxanes for tailorable polymeric scaffolds: aziridine as a clickable moiety for structural modification of materials
Literature Information
Publication Date
2017-03-15
DOI
10.1039/C7PY00317J
Impact Factor
5.582
Authors
Hyun Kyung Moon, Seohyun Kang, Hyo Jae Yoon
View Original
Abstract
This paper shows that tailorable polymeric scaffolds on a molecular scale could be achieved through the ring opening reaction of a three-membered N-heterocyclic compound, aziridine. Aziridine is incorporated into an elastomeric polymer backbone (here, PDMS) through Pt(0)-catalyzed hydrosilylation, retaining attractive features such as optical transparency and elastic properties compared to conventional PDMS. The resulting aziridine-containing PDMS is chemoselectively and regio-specifically post-modified through an orthogonal ring opening reaction of the aziridine and takes advantage of the wide substrate scope of aziridine chemistry.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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