Aziridine-functionalized polydimethylsiloxanes for tailorable polymeric scaffolds: aziridine as a clickable moiety for structural modification of materials
Literature Information
Hyun Kyung Moon, Seohyun Kang, Hyo Jae Yoon
This paper shows that tailorable polymeric scaffolds on a molecular scale could be achieved through the ring opening reaction of a three-membered N-heterocyclic compound, aziridine. Aziridine is incorporated into an elastomeric polymer backbone (here, PDMS) through Pt(0)-catalyzed hydrosilylation, retaining attractive features such as optical transparency and elastic properties compared to conventional PDMS. The resulting aziridine-containing PDMS is chemoselectively and regio-specifically post-modified through an orthogonal ring opening reaction of the aziridine and takes advantage of the wide substrate scope of aziridine chemistry.
Recommended Journals
Related Literature
X-ray emission spectroscopy: an effective route to extract site occupation of cations
Anuj Bhargava, Cindy Y. Chen, Kenneth D. Finkelstein, Richard D. Robinson
DOI: 10.1039/C8CP04628J
Protonation-induced molecular permeation at the oil/water interface in an electric field
DOI: 10.1039/C8CP04028A
Silicene-supported TiO2 nanostructures: a theoretical study of electronic and optical properties
Yesukhei Jagvaral, Qing Guo, Haiying He, Ravindra Pandey
DOI: 10.1039/C9CP00894B
Excited interatomic potential energy surfaces of Rb + He that correlate with Rb terms 52S through 72S
Amit R. Sharma, David E. Weeks
DOI: 10.1039/C8CP05550E
Vibrationally induced metallisation of the energetic azide α-NaN3
Svemir Rudić, Carole A. Morrison
DOI: 10.1039/C8CP06161K
The role of hydrophobic, aromatic and electrostatic interactions between amino acid residues and a titanium dioxide surface
Avia Leader, Daniel Mandler, Meital Reches
DOI: 10.1039/C8CP05775C
Adsorption, surface relaxation and electrolyte structure at Pt(111) electrodes in non-aqueous and aqueous acetonitrile electrolytes
Gary S. Harlow, Iain M. Aldous, Yvonne Gründer, Laurence J. Hardwick, Christopher A. Lucas
DOI: 10.1039/C9CP00499H
Infrared spectroscopy of gas phase alpha hydroxy carboxylic acid homo and hetero dimers
Yong Xia, Sifeng Chen, Peifeng Su, Zhijun Yang, Carl O. Trindle, J. L. Knee
DOI: 10.1039/C8CP05979A
Electron-withdrawing effects on the molecular structure of 2- and 3-nitrobenzonitrile revealed by broadband rotational spectroscopy and their comparison with 4-nitrobenzonitrile
William C. Bailey
DOI: 10.1039/C8CP01539B
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.











![(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure (3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure](https://static.chemtradehub.com/structs/126/1269757-29-0-c552.webp)
![1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure 1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure](https://static.chemtradehub.com/structs/143/1434747-57-5-fc0d.webp)

![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://static.chemtradehub.com/structs/210/210532-98-2-f6a7.webp)