cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)
CAS Number:
1408075-16-0
Molecular Formula:
C5H9ClF3NO
High solids content nitroxide mediated miniemulsion polymerization of n-butyl methacrylate
Literature Information
Publication Date
2017-02-09
DOI
10.1039/C7PY00067G
Impact Factor
5.582
Authors
Nicholas Ballard, Miren Aguirre, Alexandre Simula, Jose R. Leiza, José M. Asua
View Original
Abstract
The synthesis of poly(n-butyl methacrylate) by nitroxide mediated miniemulsion polymerization is described using the alkoxyamine 3-(((2-cyanopropan-2-yl)oxy)(cyclohexyl)amino)-2,2-dimethyl-3-phenylpropanenitrile. Polymerizations are successfully conducted to high conversions with high solids content (up to 52%) and molecular weight up to 60 000 g mol−1, whilst maintaining reasonable control of the reaction. It is shown that by performing the polymerization in aqueous media, problems that arise when targeting high molecular weights in bulk/solution due to build-up of nitroxide can be overcome. The ability to chain extend the resulting polymers is demonstrated and opens the possibility for synthesis of a wide range of macromolecular structures in dispersed media.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1,3(2H,4H)-Isoquinolinedione, 7-amino-4,4-dimethyl-
CAS Number:
14576-22-8
Molecular Formula:
C11H12N2O2
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