Photoexcited charge carrier dynamics of interconnected TiO2 nanoparticles: evidence of enhancement of charge separation at anatase–rutile particle interfaces
Literature Information
Daiki Shingai, Yusuke Ide, Woon Yong Sohn
The charge carrier kinetics of hydrothermally treated TiO2 nanoparticles, consisting of interconnected anatase and rutile crystallographic forms, was investigated using a heterodyne transient grating technique to obtain direct evidence of the enhancement of charge separation efficiency. We found that surface recombination arising from trapped electrons was retarded, compared with that of P25 TiO2 nanoparticles, with the aid of an increase of particle interfaces. This means that the charge separation efficiency of hydrothermally treated TiO2 nanoparticles is higher than that of P25 TiO2 nanoparticles, to which the enhanced photocatalytic performance of the hydrothermally treated TiO2 nanoparticles could be attributed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.



![(4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure (4aR,5S,6R,8aS)-5-[2-(3-Furyl)ethyl]-8a-(hydroxymethyl)-5,6-dimethyl-3,4,4a,5,6,7,8,8a-octahydro-1-naphthalenecarboxylic acid structure](https://static.chemtradehub.com/structs/184/18411-75-1-d4cd.webp)
