Heat transport through a solid–solid junction: the interface as an autonomous thermodynamic system
Literature Information
Riccardo Rurali, Xavier Cartoixà, Thuat T. Trinh, Dick Bedeaux, Signe Kjelstrup
We perform computational experiments using nonequilibrium molecular dynamics simulations, showing that the interface between two solid materials can be described as an autonomous thermodynamic system. We verify the local equilibrium and give support to the Gibbs description of the interface also away from the global equilibrium. In doing so, we reconcile the common formulation of the thermal boundary resistance as the ratio between the temperature discontinuity at the interface and the heat flux with a more rigorous derivation from nonequilibrium thermodynamics. We also show that thermal boundary resistance of a junction between two pure solid materials can be regarded as an interface property, depending solely on the interface temperature, as implicitly assumed in some widely used continuum models, such as the acoustic mismatch model. Thermal rectification can be understood on the basis of different interface temperatures for the two flow directions.
Recommended Journals

Saudi Pharmaceutical Journal

Russian Journal of General Chemistry

Chemistry Education Research and Practice

Journal of Natural Medicines

Chemical Communications

Russian Chemical Bulletin

Current Opinion in Solid State & Materials Science

Acta Materialia

Russian Journal of Coordination Chemistry

Nature Medicine
Related Literature
Reactivity of pyrrhotite (Fe9S10) surfaces: Spectroscopic studies
Yuri Mikhlin, Vladimir Varnek, Igor Asanov, Yevgeni Tomashevich, Alexander Okotrub, Alexander Livshits, Gennady Selyutin, Gennady Pashkov
DOI: 10.1039/B005372O
Benzene cation radical in mesoporous silicate: EPR detection of unusually stabilized Jahn–Teller distortion
DOI: 10.1039/A901061K
Titration microcalorimetry of micelle formation in aqueous solutions containing alkylpolyoxyethylene glycol ethers, C12H25(OCH2CH2)mOH where m=3, 4 and 5, and octadecyltrimethylammonium bromide
Jan B. F. N. Engberts, Jan Kevelam
DOI: 10.1039/B004501M
Electron paramagnetic resonance and electron spin echo study of supported and unsupported vanadium oxides
DOI: 10.1039/A900119K
Single crystal Raman microscopic study of the asbestos mineral chrysotile
DOI: 10.1039/A809238I
Infrared spectra and molecular dynamics simulations of trans-HONO isomer in an argon matrix
Tadeusz Talik, Konstantin G. Tokhadze, Zofia Mielke
DOI: 10.1039/B004161K
Excited state proton and electron transfer reactions of acridinedione dyes with amines
DOI: 10.1039/A809070J
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




