Structural reconstruction and spontaneous formation of Fe polynuclears: a self-assembly of Fe–porphyrin coordination chains on Au(111) revealed by scanning tunneling microscopy

Literature Information

Publication Date 2016-04-27
DOI 10.1039/C6CP01836J
Impact Factor 3.676
Authors

Yuxu Wang, Kun Zhou, Ziliang Shi


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Abstract

A self-assembled Fe–porphyrin coordination chain structure on a Au(111) surface is investigated by scanning tunneling microscopy (STM), revealing structural reconstruction resulting from an alternative change of molecular orientations and spontaneous formation of uniformly sized Fe polynuclears. The alternation of the molecular orientations is ascribed to the cooperation of the attractive coordination and the intermolecular steric repulsion as elucidated by high-resolution STM observations. Furthermore, chemical control experiments are carried out to determine the number of atoms in an Fe polynuclear, suggesting a tentative Fe dinuclear-module that serves not only as a coordination center to link porphyrin units together but also as a “dangling” site for further functionalization by a guest terpyridine ligand. The chain structure and the Fe polynuclears are stable up to 320 K as revealed by real-time STM scanning. Annealing at higher temperatures converts the chain structure into a two-dimensional coordination structure.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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