Photoluminescence properties of Yb2+ ions doped in the perovskites CsCaX3 and CsSrX3 (X = Cl, Br, and I) – a comparative study
Literature Information
Markus Suta, Werner Urland, Claude Daul, Claudia Wickleder
The Yb2+-doped perovskite derivatives CsMX3 (M = Ca and Sr; X = Cl, Br, and I) are ideal systems for obtaining a detailed insight into the structure–luminescence relationship of divalent lanthanides. The investigation of the respective photoluminescence properties yielded two emission bands in the violet and blue spectral range for all compounds, which are assigned to the spin-allowed and spin-forbidden 5d–4f transitions, respectively. The impact on their energetic positions is dependent on both the covalency of the Yb2+-halide bond and the corresponding bond length in agreement with expectations. The excitation spectra provide a detailed fine structure at low temperatures and can be partly interpreted separating the 4f13 core from the 5d electron in the excited state. The local crystal field in CsSrI3:Yb2+ provides a special case due to the trigonal distortion induced by the crystal structure that is clearly evident in the luminescence features of Yb2+. The structure–property relationship of several spectroscopic key quantities of Yb2+ in this series of halides is analyzed in detail and parallels the properties of Eu2+ ions doped in the given perovskites.
Related Literature
Tuning oxygen electrocatalysis via strain on LaNiO3(001)‡
Simuck F. Yuk, Valentino R. Cooper
DOI: 10.1039/C8CP02405G
Monitoring solvent dynamics and ion associations in the formation of cubic octamer polyanion in tetramethylammonium silicate solutions
Ying Chen, Nancy M. Washton, Robert P. Young, Abhijeet J. Karkamkar, James J. De Yoreo, Karl T. Mueller
DOI: 10.1039/C8CP07521B
Production of HO2 and OH radicals from near-UV irradiated airborne TiO2 nanoparticles
D. R. Moon, M. T. Baeza-Romero
DOI: 10.1039/C8CP06889E
Prediction of intrinsic two dimensional ferromagnetism realized quantum anomalous Hall effect
DOI: 10.1039/C8CP07781A
Bayesian determination of the effect of a deep eutectic solvent on the structure of lipid monolayers
Karen J. Edler, Stephen C. Parker
DOI: 10.1039/C9CP00203K
Air-stable formamidinium/methylammonium mixed lead iodide perovskite integral microcrystals with low trap density and high photo-responsivity
Guangbao Wu, Jiyu Zhou, Rui Meng, Baoda Xue, Huiqiong Zhou, Zhiyong Tang, Yuan Zhang
DOI: 10.1039/C8CP07271J
Oxygen surface exchange properties and surface segregation behavior of nanostructured La0.6Sr0.4Co0.2Fe0.8O3−δ thin film cathodes
K. Develos-Bagarinao, J. De Vero, H. Kishimoto, T. Ishiyama, K. Yamaji, T. Horita
DOI: 10.1039/C9CP00606K
Solving the Schrödinger equation of hydrogen molecules with the free-complement variational theory: essentially exact potential curves and vibrational levels of the ground and excited states of the Σ symmetry
Yusaku I. Kurokawa, Hiroyuki Nakashima, Hiroshi Nakatsuji
DOI: 10.1039/C8CP05949G
Structural studies of spray pyrolysis synthesized oxygen deficient anatase TiO2 thin films by using X-ray absorption spectroscopy
Madhusmita Sahoo, A. K. Yadav, Subrata Ghosh, S. N. Jha, D. Bhattacharyya, Tom Mathews
DOI: 10.1039/C8CP06811A
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














