Dibenzoyldiethylgermane as a visible light photo-reducing agent for CuAAC click reactions
Literature Information
Publication Date
2015-10-05
DOI
10.1039/C5PY01465D
Impact Factor
5.582
Authors
Mustafa Arslan, Gorkem Yilmaz, Yusuf Yagci
View Original
Abstract
A highly active, versatile and photoresponsive system for copper catalyzed azide–alkyne cycloaddition (CuAAC) click reaction has been developed using the dibenzoyldiethylgermane (DBDEG) photoinitiator with the copper(II) chloride (CuCl2)–N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) ligand under visible light. Selected azide and alkyne compounds with various functional groups are used to conduct the click reaction and almost quantitative yields are attained. The approach pertains to the visible light generation of germyl radicals capable of reducing Cu(II) ions to Cu(I) species to catalyze the CuAAC reactions. This strategy has been applied in the achievement of various macromolecular reactions including polymer end-group functionalization, block copolymer formation and step-growth polymerization.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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