Entropically-driven ring-opening metathesis polymerization (ED-ROMP) of macrocyclic olefins prepared from deoxycholic acid to give functionalized polymers‡
Literature Information
Publication Date
2015-04-30
DOI
10.1039/C5PY00272A
Impact Factor
5.582
Authors
Philip Hodge, Abdel Chakiri
View Original
Abstract
Three new families of macrocyclic olefins were prepared from deoxycholic acid. Two of these have a novel structure in that the bile acid unit is linked to a C20 fatty acid unit via the 3α- and 12α-positions, thus creating macrocycles with rings with a repeat unit of 29 ring atoms. Entropically-driven ring-opening methathesis polymerizations (ED-ROMPs) of the macrocycles gives polymers with free hydroxyl groups, or free methyl or t-butyl carboxylic ester groups. The latter could be converted into carboxylic acid groups by treatment with trifluoroacetic acid. The polymers form transparent hole-free films that are potentially useful for supporting cell growth.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)
CAS Number:
1260803-10-8
Molecular Formula:
C8H9BrClNO
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