The preferred upconversion pathway for the red emission of lanthanide-doped upconverting nanoparticles, NaYF4:Yb3+,Er3+
Literature Information
Taeyoung Jung, Hong Li Jo, Sang Hwan Nam, Youngho Cho, Jongwoo Kim, Hyung Min Kim, Hohjai Lee, Kang Taek Lee
Lanthanide-doped upconverting nanoparticles (UCNPs, NaYF4:Yb3+,Er3+) are well known for emitting visible photons upon absorption of two or more near-infrared (NIR) photons through energy transfer from the sensitizer (Yb3+) to the activator (Er3+). Of the visible emission bands (two green and one red band), it has been suggested that the red emission results from two competing upconversion pathways where the non-radiative relaxation occurs after the second energy transfer (pathway A, 4I15/2 → 4I11/2 → 4F7/2 → 2H11/2 → 4S3/2 → 4F9/2 → 4I15/2) or between the first and the second energy transfer (pathway B, 4I15/2 → 4I11/2 → 4I13/2 → 4F9/2 → 4I15/2). However, there has been no clear evidence or thorough analysis of the partitioning between the two pathways. We examined the spectra, power dependence, and time profiles of UCNP emission at either 980 nm or 488 nm excitation, to address which pathway is preferred. It turned out that the pathway B is predominant for the red emission over a wide range of excitation powers.
Recommended Journals
Related Literature
A kinetic and thermochemical database for organic sulfur and oxygen compounds
Caleb A. Class, Jorge Aguilera-Iparraguirre, William H. Green
DOI: 10.1039/C4CP05631K
Reaction-diffusion degradation model for delayed erosion of cross-linked polyanhydride biomaterials
Sergii Domanskyi, Katie L. Poetz
DOI: 10.1039/C5CP00473J
Controllable optical transitions of amorphous Mg and Mg–Ni films via electrochemical methods
Jiameng Qiu, Feilong Wu, Xin Jin, Xinyuan Gu, Wenbin Cai, Dalin Sun, Fang Fang
DOI: 10.1039/C5CP00800J
Structure and energetics of the anisole–Arn (n = 1, 2, 3) complexes: high-resolution resonant two-photon and threshold ionization experiments, and quantum chemical calculations
Maurizio Becucci, Jan Řezáč, Dana Nachtigallová, François Michels, Klaus Müller-Dethlefs
DOI: 10.1039/C5CP01166C
A molecular material based on electropolymerized cobalt macrocycles for electrocatalytic hydrogen evolution
Stéphane Rioual, Benoit Lescop, François Quentel, Frederic Gloaguen
DOI: 10.1039/C5CP01210D
Mesoscale simulation of the formation and dynamics of lipid-structured poly(ethylene oxide)-block-poly(methyl methacrylate) diblock copolymers
Dan Mu, Jian-Quan Li, Sheng-Yu Feng
DOI: 10.1039/C5CP00561B
Optimization of the surface properties of nanostructured Ni–W alloys on steel by a mixed silane layer
M. P. Quiroga Argañaraz, J. M. Ramallo-López, G. Benítez, A. Rubert, E. D. Prieto, L. M. Gassa, R. C. Salvarezza, M. E. Vela
DOI: 10.1039/C5CP01895A
A new schematic for poly(3-alkylthiophene) in an amorphous film studied using a novel structural index in infrared spectroscopy
N. Shioya, T. Shimoaka, K. Eda, T. Hasegawa
DOI: 10.1039/C5CP01024A
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure (2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure](https://static.chemtradehub.com/structs/250/2505001-54-5-c1e9.webp)



