Nonstoichiometry of nanocrystalline monoclinic silver sulfide

Literature Information

Publication Date 2015-04-28
DOI 10.1039/C5CP00650C
Impact Factor 3.676
Authors

S. I. Sadovnikov, A. I. Gusev


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Abstract

Powders of silver sulfide have been synthesized by chemical bath deposition from aqueous solutions of silver nitrate and sodium sulfide in the presence of sodium citrate or EDTA–H2Na2. Colloid solutions have been prepared by a chemical condensation method from the same aqueous solutions. Synthesized silver sulfide nanopowders have a monoclinic (space group P21/c) acanthite-type structure but the occupancy of the metal sublattice sites by Ag atoms is smaller than 1. Unlike coarse-crystalline silver sulfide Ag2S, silver sulfide nanopowders with particles sizes of less than ∼50 nm are nonstoichiometric, contain vacant sites in the metal sublattice and have a composition of ∼Ag1.93S.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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