1,3(2H,4H)-Isoquinolinedione, 7-amino-4,4-dimethyl-
CAS Number:
14576-22-8
Molecular Formula:
C11H12N2O2
The synthesis of microporous polymers using Tröger's base formation
Literature Information
Publication Date
2014-06-20
DOI
10.1039/C4PY00609G
Impact Factor
5.582
Authors
Mariolino Carta, Richard Malpass-Evans, Matthew Croad, Yulia Rogan, Michael Lee, Ian Rose, Neil B. McKeown
View Original
Abstract
A step-growth polymerisation based on the formation of Tröger's base, performed by simple reaction of a suitable aromatic diamine monomer with dimethoxymethane in trifluoroacetic acid, provides polymers of high average molecular mass. The properties of the resulting polymers can be tailored by the choice of monomer. In particular, the Tröger's base polymerisation is highly suited to the preparation of soluble polymers of intrinsic microporosity (PIMs) due to the resulting fused-ring TB linking group, which is both highly rigid and prohibits conformational freedom.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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