4-Methyl-3-morpholinecarboxylic acid hydrochloride (1:1)
CAS Number:
1240518-90-4
Molecular Formula:
C6H12ClNO3
Heterogeneous organocatalysts composed of microporous polymer networks assembled by Tröger's base formation
Literature Information
Publication Date
2014-06-20
DOI
10.1039/C4PY00608A
Impact Factor
5.582
Authors
Mariolino Carta, Matthew Croad, Keith Bugler, Kadhum J. Msayib, Neil B. McKeown
View Original
Abstract
Microporous polymer networks are assembled from triamino-triptycene monomers using a polymerisation reaction based on the formation of Tröger's base (TB). The highly rigid triptycene units ensure that the polymer networks demonstrate significant intrinsic microporosity as demonstrated by apparent surface areas of up to 1000 m2 g−1. These networks act as heterogeneous basic catalysts which enhance greatly the rate of a model Knovenagel reaction between malonontrile and benzaldehyde. Indeed, the microporous networks, which possess a high concentration of basic sites, enhance the rate of the Knovenagel reaction even more efficiently than using Tröger's base as a homogeneous catalyst.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide
CAS Number:
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Molecular Formula:
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